Selective Template Removal by Thermal Depolymerization to Obtain Mesostructured Molybdenum Oxycarbide

The carbon content of mesostructured organic‐inorganic hybrid material of a cylindrical block copolymer template of poly(2‐vinylpyridine)‐block‐poly(allyl methacrylate) (P2VP‐b‐PAMA) and ammonium paramolybdate (APM) could be reduced by thermal depolymerization. By calcination in vacuo at 320 °C the PAMA core can be completely removed while the remaining P2VP brush preserves the mesostructure. The P2VP‐APM composite can then be carburized in‐situ to MoO_xC_y in a second pyrolysis step without any additional carbon source but P2VP. The molybdenum oxycarbide nanotubes obtained, form hierarchically porous non‐woven structures, which were tested as catalyst in the decomposition of NH₃. They proved to be catalytically active at temperatures above 450 °C. The activation energy was estimated from an Arrhenius Plot to be 127 kJ · mol^–1.     

INCREMENTAL MICRO-MECHANICAL MODEL OF PLAIN WOVEN FABRIC

I. INTRODUCTION Previous research on woven fabric ignored the micro-weaving structures in fabric and modeled thewoven fabric as a ?exible orthotropic plate[1??3]. However, such a model is unable to predict certainbuckling phenomena of fabric commonly ob…     

Annealing effect in glass woven fabric composites,Part II. Bending properties

Effects of annealing on bending properties of composites reinforced with plain glass woven fabrics that were treated with different concentrations of silane coupling agent were investigated in this paper. Bending strength increased by annealing in the specimen treated with lower silane concentration. Higher annealing temperature in a range from 80°C to 150°C led to higher bending strength. Then, the fracture mode changed from a micro-crack type (low strength type) to a branched matrix crack type (high strength type) by annealing.     

对二维编织复合材料弹性、热、强度及失效分析模型的评论

纺织结构作为聚合物复合材料的增强相在许多工业应用中变得非常重要,例如在航海与航空 领域中,由于其刚度及强度与其重量的高比值而倍受欢迎.由于工业及工程应用的需求, 研究纺织复合材料的弹性性质及失效行为变得非常重要.这篇文章重点评论了关于二维编织复合材料弹性、热、强度及失效分析的数值及解析模型,给出了主要的建模技术及方法. 同时也简单给出了编织复合材料从最初的一维模型到最近三维模型的发展.本文的目的不是对所 论模型的数学方法进行详细分析,而是告知研究者关于先前工作的主要思想. 这篇评论总共引用了122篇文献.      

Local elastodynamic stresses in the unit cell of a woven fabric composite

Summary A theoretical study of the local elastodynamic stresses of woven fabric composites under dynamic loadings is presented in this article. The analysis focuses on the unit cell of an orthogonal woven fabric composite, which is composed of two sets of mutually orthogonal yarns of either the same fiber (nonhybrid fabric) or different fibers (hybrid fabric) in a matrix material. Using the mosaic model for simplifying woven fabric composites and a shear lag approach to account for the inter-yarn deformation, a one-dimensional analysis has been developed to predict the local elastodynamic and elastostatic behavior. The initial and boundary value problems are formulated and then solved using Laplace transforms. Closed form solutions of the dynamic displacements and stresses in each yarn and the bond shearing stresses at the interfaces between adjacent yarns are obtained in the time domain for any type of in-plane impact loadings. When time tends to infinity, the dynamic solutions approach to their corresponding static solutions, which are also developed in this article. Solutions of certain special cases are identical to those reported in the literature. Lastly, the dynamic stresses and bond shearing stresses of plain weave composites subjected to step uniform impacts are presented and discussed as an example of the general analytical model. Received 3 May 1999; accepted for publication 22 September 1999     

含72元环的二维网状结构超分子配合物的合成与结构

用自组装方法合成具有特殊网状结构及光学、电学、磁学、离子或分子交换、催化等性能的化合物的分子工程学和超分子化学近年来成为人们研究的热点,并已取得了很大进展［１,２］．当前常用的一种三角架结构单元是刚性芳基三角架配体［３～５］,而对柔性芳基三角架配体及...     

倾斜摆动条件下衬垫改性对自润滑关节轴承摩擦学性能的影响

本文中通过对PTFE纤维/芳纶纤维混合编织衬垫分别进行稀土处理和丙酮处理,研究了在倾斜摆动条件下衬垫改性对自润滑关节轴承摩擦学性能的影响,并用扫描电子显微镜(SEM)以及三维形貌仪分析了衬垫磨损表面微观形貌.研究结果表明:与未经改性处理衬垫的轴承相比,经稀土处理和丙酮处理后自润滑关节轴承减磨耐磨性能均得到提高,其中在高摆频工况下,衬垫经稀土处理后自润滑关节轴承减摩耐磨性能得到更大程度的提高;稀土处理轴承衬垫仅出现轻微黏着磨损,这是由于稀土处理过程增强了衬垫层的自润滑功能.     

On stabilization of implosion of condensed liners

This paper considers various experimental designs on the Atlas facility to study the physics of liners and determine the optimum conditions of their stable motion. In one of the versions, in comparison with the Liner Demonstration series of experiments, in which unstable liner motion was observed, it is proposed to reduce the initial liner radius without changing its mass, which, according to two-dimensional calculations, should to lead to more stable motion of the liner with unchanged velocity. It is also proposed to perform an experiment in which periodic perturbations at a certain wavelength are created on the outer surface of the liner with a simultaneous increase in its thickness. According to calculations, the growth of chaotic perturbations is stabilized in this case with the preservation of the liner velocity. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 50, No. 3, pp. 3–14, May–June, 2009.     

基于渐进均匀化的平纹编织复合材料低速冲击多尺度方法

针对平纹编织复合材料低速冲击响应和损伤问题,提出了一种多尺度分析方法. 首先, 建立微观尺度单胞模型,引入周期性边界条件,采用最大主应力失效准则和直接刚度退化模型表征纤维丝和基体的损伤起始与演化,预测了纤维束的弹性性能和强度性能. 其次,将这些性能参数代入介观尺度单胞模型,基于Hashin和Hou的混合失效准则以及连续介质损伤模型对介观尺度单胞进行6种边界条件下的渐进损伤模拟.然后采用渐进均匀化方法,以介观尺度单胞为媒介预测了0$^\circ$和90$^\circ$子胞的性能参数,并建立平纹编织复合材料的子胞模型,进而扩展成为材料的宏观尺度低速冲击模型. 在此基础上,研究了平纹编织复合材料低速冲击下的力学响应与损伤特征.结果表明:宏观冲击仿真和试验吻合较好, 验证了多尺度方法的正确性;最大接触力、材料吸能和分层面积均随冲击能量的增大而增大,分层损伤轮廓逐渐从椭圆形向圆形转化;基体拉伸和压缩损伤的长轴方向分别与子胞材料主方向正交和一致,损伤面积前者远大于后者.